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Alkyl‐ and Arylrhenium Trioxides
Author(s) -
Herrmann Wolfgang A.,
Romao Carlos C.,
Fischer Richard W.,
Kiprof Paul,
de Méric de Bellefon Claude
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199101851
Subject(s) - thermal stability , alkyl , chemistry , thermal , thermodynamics , organic chemistry , physics
The thermal stability of the ethyl, isobutyl, silaneopentyl and phenyl complexes 1 – 4 is surprising. At room temperature they are colorless, very volatile liquids and solids and are formed in a procedure (equation (a)), which is quite general.