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Unsaturated Tin Compounds: Generation and Reactivity of Me 2 Sn = C(SiMe 3 ) 2 and Me 2 Sn = N(Si t Bu 2 Me)
Author(s) -
Wiberg Nils,
Vasisht ShamKumar
Publication year - 1991
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199100931
Subject(s) - tin , reactivity (psychology) , trapping , chemistry , salt (chemistry) , germanium compounds , organic chemistry , silicon , germanium , medicine , ecology , alternative medicine , pathology , biology
Stannaethene 1, which is hardly stabilized electronically , was obtained by salt elimination and its existence was shown by trapping reactions with 2,3‐dimethylbutadiene and azido(di‐ tert ‐butyl) methylsilane. Stannanimine 2 , formed from the azidosilane, can be “stored” as the cycloadduct 3.