Preparation and Structure of [SeW(PSe 4 )(PSe 2 )] 2⊖ ; a Cluster Containing a Heteroallylic PSe       2    ⊖     Unit | Zendy

O'Neal Samuel C. | Zendy; Pennington William T. | Zendy; Kolis Joseph W. | Zendy

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Preparation and Structure of [SeW(PSe 4 )(PSe 2 )] 2⊖ ; a Cluster Containing a Heteroallylic PSe 2 ⊖ Unit

Author(s) -

O'Neal Samuel C.,

Pennington William T.,

Kolis Joseph W.

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199014861

Subject(s) - ligand (biochemistry) , chemistry , chalcogenide , crystallography , nitrile , tetrahedron , denticity , cluster (spacecraft) , bent molecular geometry , tungsten , coordination sphere , crystal structure , stereochemistry , organic chemistry , computer science , biochemistry , receptor , programming language

A nitrile analogous lower coordinated phosphorus chalcogenide is the most surprising structural feature of the anionic wolfram complex 1 . The bent PSe 2 ⊖unit is bonded side‐on to the tungsten; a terminal seleno‐ligand and a bidentate tetrahedral PSe 4 3⊖ligand. Complete the coordination sphere of the metal center.

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