Electrical and Magnetic Properties and X‐Ray Structure of a Highly Conductive 4:1 Complex of Tetracyanoquinodimethane and a Tetrathiafulvalene Derivative | Zendy

Bryce Martin R. | Zendy; Moore Adrian J. | Zendy; Hasan Masihul | Zendy; Ashwell Geoffrey J. | Zendy; Fraser Alexander T. | Zendy; Clegg William | Zendy; Hursthouse Michael B. | Zendy; Karaulov A. I. | Zendy

Premium

Electrical and Magnetic Properties and X‐Ray Structure of a Highly Conductive 4:1 Complex of Tetracyanoquinodimethane and a Tetrathiafulvalene Derivative

Author(s) -

Bryce Martin R.,

Moore Adrian J.,

Hasan Masihul,

Ashwell Geoffrey J.,

Fraser Alexander T.,

Clegg William,

Hursthouse Michael B.,

Karaulov A. I.

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199014501

Subject(s) - tetrathiafulvalene , tetracyanoquinodimethane , moiety , anthracene , dication , derivative (finance) , electron acceptor , stoichiometry , electrical conductor , conjugated system , chemistry , materials science , crystallography , acceptor , photochemistry , polymer chemistry , stereochemistry , molecule , organic chemistry , condensed matter physics , polymer , physics , financial economics , economics , composite material

Despite strong twisting of the conjugated system , the tetrathiafulvalene homologue 1 reacts with the electron acceptor tetracyanoquinonodimethane to give the dication 1 2⊕ . The anthracene moiety is embedded in the 1 2⊕ [(TCNQ) 4 ] 2⊖ , and the dithiol rings are twisted 86° with respect to the anthracene plane: The 1:4 stoichiometry of the highly conductive salt (σ 300K = 60S cm −1 ) is very unusual for TCNQ complexes.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research