Decameric and Dodecameric Sodium Amides and an Organosodium Amide with Stack Structures: [Na 10  (NMe 2 ) 10 (tmeda) 4 ],|Na 12 (NMe 2 ) 12 (tmeda) 4 |, and [Na 12 (NMe 2 ) 10 (CH 2 C 6 H 4 Me) 2 (tmeda) 4 ] | Zendy

Lorenzen Nis Peter | Zendy; Kopf Jürgen | Zendy; Olbrich Falk | Zendy; Schümann Uwe | Zendy; Weiss Erwin | Zendy

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Decameric and Dodecameric Sodium Amides and an Organosodium Amide with Stack Structures: [Na 10 (NMe 2 ) 10 (tmeda) 4 ],|Na 12 (NMe 2 ) 12 (tmeda) 4 |, and [Na 12 (NMe 2 ) 10 (CH 2 C 6 H 4 Me) 2 (tmeda) 4 ]

Author(s) -

Lorenzen Nis Peter,

Kopf Jürgen,

Olbrich Falk,

Schümann Uwe,

Weiss Erwin

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199014411

Subject(s) - amide , stack (abstract data type) , chemistry , lithium (medication) , ring (chemistry) , sodium , crystallography , stereochemistry , organic chemistry , computer science , medicine , endocrinology , programming language

The oligomeric sodiumamides 1–3 , which were formed during attempts to metalate hydrocarbons with n ‐butylsodium in the presence of teteramethylethylenediamine, have stacked ring structures. Correspondingly structured lithium amides are not known; rather, in this case ladder structures should be preferred.

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