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Doubly Bridged Prismanes, Dewar Benzenes and Benzene Derivatives from Cyclooctyne and 1, 8‐Cyclotetradecadiyne: En Route to Propella[n 3 ]prismanes
Author(s) -
Gleiter Rolf,
Treptow Björn
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199014271
Subject(s) - benzene , chemistry , materials science , photochemistry , organic chemistry
The highly strained Dewer‐benzene 1 and the prismane 2 can be obtained from Cyclooctyne in a few steps. 2 is formed by irradiation of 1 with long wavelength light; at λ = 250 nm only polymers are formed, presumably via the corresponding [5]paracyclophane.
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