Premium
s ‐ trans ‐1, 3‐Dienes as Ligands for Cationic Group 8 Metal Centers
Author(s) -
Benyunes Stephen A.,
Day Jeremy P.,
Green Michael,
AlSaadoon Abdul Wahab,
Waring Tracey L.
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199014161
Subject(s) - cationic polymerization , diene , chemistry , catalysis , metal , conjugated system , conjugated diene , stereochemistry , group (periodic table) , medicinal chemistry , polymer chemistry , organic chemistry , polymer , natural rubber , monomer
1,3‐Dienes very frequently assume an s‐ cis ‐conformation upon coordination to metal centers. The Ru‐complex 1 is the first cationic s‐ trans ‐diene complex which is stable in solution at room temperature. Such complexes are conceivable as reactive intermediates in the catalytic reaction of conjugated dienes.