Synthesis and Cycloadditions of Monomeric Selenobenzophenone | Zendy

Erker Gerhard | Zendy; Hock Regina | Zendy; Krüger Carl | Zendy; Werner Stefan | Zendy; Klärner FrankGerrit | Zendy; ArtschwagerPerl Uwe | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis and Cycloadditions of Monomeric Selenobenzophenone

Author(s) -

Erker Gerhard,

Hock Regina,

Krüger Carl,

Werner Stefan,

Klärner FrankGerrit,

ArtschwagerPerl Uwe

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199010671

Subject(s) - monomer , chemistry , diene , solid state , hexa , product (mathematics) , high pressure , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , polymer , thermodynamics , physics , natural rubber , geometry , mathematics

Selenobenzophenone (1), prepared from Ph 2 C PPh 3 and Se, is monomeric in solution and dimeric in the solid state . Cycloadditions of dienes to 1 proceed at room temperature under normal pressure as multistep reactions, as shown by the exclusive formation of cis ‐ 2 from both trans, trans‐ and cis, trans ‐hexa‐2,4‐diene. When the pressure is raised to about 12 kbar, cis, trans ‐hexadiene affords 60% of trans ‐ 2 , the product of the concerted hetero‐Diels–Alder reaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research