Boroboration of CO with Tri‐ tert ‐butylazadiboriridine | Zendy

Paetzold Peter | Zendy; RedenzStormanns Burkhard | Zendy; Boese Roland | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Boroboration of CO with Tri‐ tert ‐butylazadiboriridine

Author(s) -

Paetzold Peter,

RedenzStormanns Burkhard,

Boese Roland

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199009001

Subject(s) - steric effects , analogy , ring (chemistry) , chemistry , reactivity (psychology) , cleavage (geology) , bond cleavage , product (mathematics) , stereochemistry , medicinal chemistry , materials science , mathematics , organic chemistry , catalysis , philosophy , geometry , linguistics , alternative medicine , pathology , fracture (geology) , composite material , medicine

The formation of the unexpected, exotic product 2 in the reaction of the sterically shielded Hückel‐aromatic three‐membered ring compound 1 can plausibly be. explained by way of analogy. With CO from Fe(CO) 5 , a completely different, likewise unexpected product is obtained, whose formation involves cleavage of the CO triple bond, and even at −30°C! Both results throw valuable light the reactivity of CO.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research