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Oxidative Addition of Phosphorus Ylides to Ru 3 (CO) 12
Author(s) -
Bohle D. Scott,
Heineke Daniel,
Tiripicchio Antonio,
Camellini Marisa Tiripicchio,
Vahrenkamp Heinrich
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199008961
Subject(s) - cluster (spacecraft) , phosphorus , chemistry , oxidative addition , methane , ligand (biochemistry) , ruthenium , sequence (biology) , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , receptor , computer science , programming language
The Ru 3 C‐cluster 1 with a C‐bonded phosphane ligand is the final product of the reaction of Ph 3 PCH 2 with Ru 3 (CO) 12 . This cluster could be structurally characterized, as also could a phosphonio enolate isolated as intermediate. The formation of 1 completes the use of all methane H‐atoms in the sequence CH 4 → CH 3 I → CH 2 = PPh 3 → 1 .