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Synthesis and Characterization of the Linear Trinuclear Complexes [M 3 II (O 2 CCH 3 ) 6 (biphme) 2 ], M = Mn, Fe
Author(s) -
Rardin R. Lynn,
Bino Avi,
Poganiuch Peter,
Tolman William B.,
Liu Shuncheng,
Lippard Stephen J.
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199008121
Subject(s) - denticity , carboxylate , crystallography , oxygen atom , chemistry , atom (system on chip) , characterization (materials science) , stereochemistry , molecule , crystal structure , materials science , nanotechnology , organic chemistry , computer science , embedded system
A Mn 3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the Mn II title complex 1 . Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms.