A Paramagnetic μ‐Methylene Complex with a Short Cr  III  Cr  III   Bond | Zendy

Noh Seok Kyun | Zendy; Heintz Robert A. | Zendy; Janiak Christoph | Zendy; Sendlinger Shawn C. | Zendy; Theopold Klaus H. | Zendy

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A Paramagnetic μ‐Methylene Complex with a Short Cr III Cr III Bond

Author(s) -

Noh Seok Kyun,

Heintz Robert A.,

Janiak Christoph,

Sendlinger Shawn C.,

Theopold Klaus H.

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199007751

Subject(s) - atomic orbital , magnetic moment , decomposition , paramagnetism , chemistry , methylene , electron , crystallography , condensed matter physics , physics , quantum mechanics , medicinal chemistry , organic chemistry

A CrCr distance of only 2.394(1) Å was found in the binuclear complex 2 , obtainable by decomposition of 1 . Extended Hückel calculations gave five energetically similar frontier orbitals for six electrons. The high magnetic moment (μ eff = 3.3μ B ) indicates the presence of a CrCr single bond.

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