Synthesis and Structure of Annelated Carbon Rings Containing a Bridgehead Transition Metal | Zendy

O'Connor Joseph M. | Zendy; Pu Lin | Zendy; Chadha Raj | Zendy

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Synthesis and Structure of Annelated Carbon Rings Containing a Bridgehead Transition Metal

Author(s) -

O'Connor Joseph M.,

Pu Lin,

Chadha Raj

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199005431

Subject(s) - oxonium ion , carbene , iridium , carbon atom , chemistry , carbon fibers , transition metal , resonance (particle physics) , polymer chemistry , organic chemistry , materials science , ring (chemistry) , physics , atomic physics , catalysis , ion , composite number , composite material

An iridium atom in a bridgehead position is the most unusual feature of 2 , which was obtained in place of the anticipated carbene vinylidene complex upon reaction of 1 with propiolic acid. Equally surprising is the fact that 2 must be regarded as an oxonium system rather than as a carbene, the most obvious resonance alternative. R CO 2 CH 3 .

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