A New Route to 1,3‐Diphospholide Ions. Synthesis and X‐Ray Structure Analysis of a 1,3‐Diphosphaferrocene | Zendy

Maigrot Nicole | Zendy; Ricard Louis | Zendy; Charrier Claude | Zendy; Mathey François | Zendy

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A New Route to 1,3‐Diphospholide Ions. Synthesis and X‐Ray Structure Analysis of a 1,3‐Diphosphaferrocene

Author(s) -

Maigrot Nicole,

Ricard Louis,

Charrier Claude,

Mathey François

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199005341

Subject(s) - cationic polymerization , ion , atom (system on chip) , chemistry , x ray , crystallography , stereochemistry , combinatorial chemistry , polymer chemistry , physics , organic chemistry , computer science , optics , embedded system

New perspectives are opened by the synthesis of 1,3‐diphospholide ions such as 2 from 1,2‐diphosphetenes like 1 . The Ph substituents of 2 are easily varied by choosing an appropriately substituted starting material; even the H atom in 2 is subject to replacement. Compound 2 reacts with a cationic cyclopentadienyliron species to give the corresponding terrocene analogue.

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