Organometallic Macrocycles: Synthesis and Molecular Structure of Trimeric Tartratodiruthenium Complexes | Zendy

SüssFink Georg | Zendy; Wolfender JeanLuc | Zendy; Neuman Frank | Zendy; StoeckliEvans Helen | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Organometallic Macrocycles: Synthesis and Molecular Structure of Trimeric Tartratodiruthenium Complexes

Author(s) -

SüssFink Georg,

Wolfender JeanLuc,

Neuman Frank,

StoeckliEvans Helen

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199004291

Subject(s) - ring (chemistry) , chemistry , organometallic chemistry , crystallography , tartaric acid , group 2 organometallic chemistry , stereochemistry , metal , molecule , crystal structure , organic chemistry , citric acid

A ring containing six Ru atoms, six O atoms, and 12 C atoms occurs in the structure of compound 1 , which is characterized by dinuclear metallic units joined through tartrato ligands. 1 is remarkably easy to prepare from Ru 3 (CO) 12 and ( R,R )‐, ( S,S )‐ or ( R,S )‐tartaric acid, with configuration being maintained in the course of the reaction. Observed yields are of the order of 80% The compounds 1 are to be regarded as organometallic macrocycles with chiral structural units.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research