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Synthesis and Structure of the Novel μ 2 ‐Carbido Complex [(TPP)FeCRe(CO) 4 Re(CO) 5 ]
Author(s) -
Beck Wolfgang,
Knauer Wolfgang,
Robl Christian
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199003181
Subject(s) - dichlorocarbene , carbide , chemistry , crystallography , stereochemistry , medicinal chemistry , organic chemistry
The title compound 2 contains an FeCReRe unit . This 1,3‐dimetallaallene is a novel example of the rare carbide‐bridged complexes. 2 is formed on reaction of the dichlorocarbene complex 1 with pentacarbonylrhenate (TPP tetra‐phenylporphyrinate).