Premium
On a (1,4‐Diazabutadiene)bis(ethene)nickel(0) Complex and Related Compounds
Author(s) -
Bonrath Werner,
Pörschke Klaus R.,
Michaelis Stephan
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199002981
Subject(s) - cyclooctatetraene , nickel , chemistry , non blocking i/o , atom (system on chip) , photochemistry , tris , medicinal chemistry , molecule , catalysis , organic chemistry , computer science , embedded system , biochemistry
Deep‐violet cubic crystals of an 18e‐Ni o complex with two ethene ligands are formed when tris(ethene)nickel(0) is allowed to react with 1,4‐bis(2,6‐diisopropylphenyl)‐1,4‐diazabutadiene (see 1 ). The ethene ligands of this extremely reactive complex can be replaced, for example, by hexadiene and cyclooctatetraene. Attempted coupling of the two ethene ligands with the Ni atom to give a nickelacyclopentane complex failed.