On a (1,4‐Diazabutadiene)bis(ethene)nickel(0) Complex and Related Compounds | Zendy

Bonrath Werner | Zendy; Pörschke Klaus R. | Zendy; Michaelis Stephan | Zendy

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On a (1,4‐Diazabutadiene)bis(ethene)nickel(0) Complex and Related Compounds

Author(s) -

Bonrath Werner,

Pörschke Klaus R.,

Michaelis Stephan

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199002981

Subject(s) - cyclooctatetraene , nickel , chemistry , non blocking i/o , atom (system on chip) , photochemistry , tris , medicinal chemistry , molecule , catalysis , organic chemistry , computer science , embedded system , biochemistry

Deep‐violet cubic crystals of an 18e‐Ni o complex with two ethene ligands are formed when tris(ethene)nickel(0) is allowed to react with 1,4‐bis(2,6‐diisopropylphenyl)‐1,4‐diazabutadiene (see 1 ). The ethene ligands of this extremely reactive complex can be replaced, for example, by hexadiene and cyclooctatetraene. Attempted coupling of the two ethene ligands with the Ni atom to give a nickelacyclopentane complex failed.

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