Si[(Me 2 P) 2 C(SiMe 3 )] 2 , a Stable σ‐Bonded Compound Containing Divalent Silicon | Zendy

Karsch Hans H. | Zendy; Keller Ursula | Zendy; Gamper Siegfried | Zendy; Müller Gerhard | Zendy

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Si[(Me 2 P) 2 C(SiMe 3 )] 2 , a Stable σ‐Bonded Compound Containing Divalent Silicon

Author(s) -

Karsch Hans H.,

Keller Ursula,

Gamper Siegfried,

Müller Gerhard

Publication year - 1990

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199002951

Subject(s) - tin , silicon , germanium , crystallography , divalent , bipyramid , divalent metal , center (category theory) , germanium compounds , chemistry , carbon group , silicon germanium , materials science , stereochemistry , crystal structure , metal , group (periodic table) , organic chemistry

New reaction paths in silicon chemistry could be opened up by the title compound 1 , in which the diphosphinomethide ligands are σ‐bonded to the Si II center. Like the analogous germanium and tin compounds, 1 is pseudotrigonal‐bipyramidal; remarkably, however, 1 is structurally similar to the tin compound.

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