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Inverse Amine‐Stabilized Sulfenes F 2 CSO 2 and FHCSO 2
Author(s) -
Pritzkow Hans,
Rall Klaus,
ReimannAndersen Stefan,
Sundermeyer Wolfgang
Publication year - 1990
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199000601
Subject(s) - aminolysis , electrophile , chemistry , amine gas treating , adduct , atom (system on chip) , stereochemistry , organic chemistry , computer science , catalysis , embedded system
An electrophilic C atom distinguishes the two title sulfenes from other sulfenes, in which the S atom is electrophilic. This follows from the structures of the Et 3 N adducts. which in these cases are present as zwitterions 1 and 2 respectively, and do not have the general structure A. 2 is formed from FH 2 CSO 2 C1 and Et 3 N, 1 by aminolysis of the dithietane 3 .