Inter‐ and Intramolecular Photochemical CH Activation in Matrices and in Solution with (η 6 ‐Arene)(carbonyl)osmium Complexes | Zendy

McCamley Andrew | Zendy; Perutz Robin N. | Zendy; Stahl Stefan | Zendy; Werner Helmut | Zendy

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Inter‐ and Intramolecular Photochemical CH Activation in Matrices and in Solution with (η 6 ‐Arene)(carbonyl)osmium Complexes

Author(s) -

McCamley Andrew,

Perutz Robin N.,

Stahl Stefan,

Werner Helmut

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198916901

Subject(s) - osmium , intramolecular force , chemistry , photochemistry , intermolecular force , toluene , medicinal chemistry , stereochemistry , catalysis , molecule , organic chemistry , ruthenium

Oxidative addition of CH 4 —i.e., inter molecular C‐H activation—as well as intrra molecular C‐H activation have been achieved photochemically with arene(carbonyl)osmium complexes. Compounds 1 and 2 lead to 3 through elimination of CO or H 2 in a CH 4 matrix, while 4 isomerizes in a matrix as well as in toluene solution to give 5 ; RMe.

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