Double‐Stranded Molecules: A [6] Beltene Derivative and the Corresponding Open‐Chain Polymer | Zendy

Godt Adeiheid | Zendy; Enkelmann Volker | Zendy; Schlüter ArnulfDieter | Zendy

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Double‐Stranded Molecules: A [6] Beltene Derivative and the Corresponding Open‐Chain Polymer

Author(s) -

Godt Adeiheid,

Enkelmann Volker,

Schlüter ArnulfDieter

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198916801

Subject(s) - ribbon , polymer , derivative (finance) , chain (unit) , molecule , polymer chemistry , materials science , polymerization , degree of polymerization , crystallography , polymer science , chemistry , composite material , physics , organic chemistry , astronomy , financial economics , economics

Simple heating of a dime/dienophile precursor can provide either gram‐quantities of the [6] beltene derivative 1 or a ribbon‐like polymer. Compound 1 is stereochemically uniform, and in the crystalline state it takes the form of flattened, double‐stranded rings. The morphology of the ribbon polymer (with a polymerization degree of 24–330!) resembles a “two‐dimensional coil.” R (CH 2 ) 6 .

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