A Pyrrolophanediene‐Porphycene Redox System | Zendy

Vogel Emanuel | Zendy; Grigat Ilona | Zendy; Köcher Matthias | Zendy; Lex Jahann | Zendy

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A Pyrrolophanediene‐Porphycene Redox System

Author(s) -

Vogel Emanuel,

Grigat Ilona,

Köcher Matthias,

Lex Jahann

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198916551

Subject(s) - annulene , redox , planar , chemistry , analogy , oxidation reduction , photochemistry , stereochemistry , organic chemistry , computer science , computer graphics (images) , philosophy , biochemistry , linguistics

In analogy to the isophlorines discussed by Woodward , N,N ′‐dihydroporphycenes should be regarded as [4n]annulenes, which explains their extremely facile oxidation to the aromatic porphycenes. Compound 1 is the first example of an N,N ′‐dihydroporphycene to be synthesized. The phane‐like, colorless 1 and the deep violet, planar 2 constitute a redox system.

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