A Polymolecular Donor–Acceptor Stack Made of Paraquat and a 1, 5‐Dihydroxynaphthalene‐ Derived Crown Ether | Zendy

Ortholand JeanYves | Zendy; Slawin Alexandra M. Z. | Zendy; Spencer Neil | Zendy; Stoddart J. Fraser | Zendy; Williams David J. | Zendy

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A Polymolecular Donor–Acceptor Stack Made of Paraquat and a 1, 5‐Dihydroxynaphthalene‐ Derived Crown Ether

Author(s) -

Ortholand JeanYves,

Slawin Alexandra M. Z.,

Spencer Neil,

Stoddart J. Fraser,

Williams David J.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198913941

Subject(s) - paraquat , crown ether , acceptor , stack (abstract data type) , naphthalene , conductor , ring (chemistry) , solid state , chemistry , ether , materials science , organic chemistry , physics , computer science , composite material , condensed matter physics , ion , programming language

Paraquat dications enclosed sandwichlike within and between dodecaoxa[16.16]naphthalenophane macrocycles characterize the solid‐state 1:2 complex 1 , which forms continuous donor–acceptor stacks. The distances between the ring planes of the naphthalene and paraquat units are uniformly short. The novel complex 1 is of particular interest as a potential organic conductor.

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