Aggregation of Metal Ions with Functionalized, Calixarenes: Synthesis and Structure of an, Octanuclear Copper( I ) Chloride Complex | Zendy

Floriani Carlo | Zendy; Jacoby Denis | Zendy; ChiesiVilla Angiola | Zendy; Guastini Carlo | Zendy

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Aggregation of Metal Ions with Functionalized, Calixarenes: Synthesis and Structure of an, Octanuclear Copper( I ) Chloride Complex

Author(s) -

Floriani Carlo,

Jacoby Denis,

ChiesiVilla Angiola,

Guastini Carlo

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198913761

Subject(s) - tetramer , copper , ligand (biochemistry) , chemistry , calixarene , derivative (finance) , metal , chloride , ion , crystallography , metal ions in aqueous solution , inorganic chemistry , stereochemistry , molecule , polymer chemistry , organic chemistry , receptor , biochemistry , financial economics , economics , enzyme

New phosphorus‐containing donor ligands capable of coordinating to several metal atoms are derived from a calix[4]arene derivative. This ligand is a cyclic tetramer consisting of m ‐linked (2‐R 2 PO‐5‐ t BuC 6 H 2 )‐CH 2 units. Shown on the right is half of the centrosymmetric complex formed upon reaction of this ligand with [Cu(CO)Cl] n . Four differently bonded copper atoms are present (the ligands R are omitted).

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