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Generation and Ionization Pattern of the Iso(valence)electronic Compounds CIP(O) 2 and CIP(S) 2
Author(s) -
Meisel Manfred,
Bock Hans,
Solouki Bahman,
Kremer Matthias
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198913731
Subject(s) - valence (chemistry) , ionization , betaine , planar , chemistry , dissociation (chemistry) , valence electron , spectral line , electron , ionization energy , electron ionization , atomic physics , analytical chemistry (journal) , computational chemistry , ion , physics , organic chemistry , computer science , computer graphics (images) , quantum mechanics , astronomy
The title compounds may be regarded as a missing link in the series of planar 24‐electron compounds Cl 3 B, Cl 2 CS, ClPS 2 , ClPO 2 , C1NO 2 , SO 3 . They are readily accessible by dissociation of betaine 1 . The electron distribution in the compounds of this series is discussed on the basis of PE spectra. The positively charged centers are surrounded in a starlike fashion by substituents that are mostly negatively charged (X O, S).
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