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Two Novel Polyoxomolybdates Containing the (MoNO) 3⊕ Unit: [Mo 5 Na(NO)O 13 (OCH 3 ) 4 ] 2⊖ and [Mo 6 (NO)O 18 ] 3⊖
Author(s) -
Gouzerh Pierre,
Jeannin Yves,
Proust Anna,
Robert Francis
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198913631
Subject(s) - hydroxylamine , crystallography , molybdenum , methanol , chemistry , physics , stereochemistry , inorganic chemistry , organic chemistry
The first polyoxomolybdates with an Mo II NO instead of an Mo IV O group are compounds 2 and 3 . They were obtained by reductive nitrosylation of complex 1 with hydroxylamine in methanol. Pentamolybdate 2 is transformed into hexamolybdate 3 upon dissolution, for example in CH 2 Cl 2 . The structures of both title compounds are derived from the Lindgvist structure [Mo 6 O 19 ] 2⊖ .