Two Novel Polyoxomolybdates Containing the (MoNO) 3⊕  Unit: [Mo 5 Na(NO)O 13 (OCH 3 ) 4 ] 2⊖  and [Mo 6 (NO)O 18 ] 3⊖ | Zendy

Gouzerh Pierre | Zendy; Jeannin Yves | Zendy; Proust Anna | Zendy; Robert Francis | Zendy

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Two Novel Polyoxomolybdates Containing the (MoNO) 3⊕ Unit: [Mo 5 Na(NO)O 13 (OCH 3 ) 4 ] 2⊖ and [Mo 6 (NO)O 18 ] 3⊖

Author(s) -

Gouzerh Pierre,

Jeannin Yves,

Proust Anna,

Robert Francis

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198913631

Subject(s) - hydroxylamine , crystallography , molybdenum , methanol , chemistry , physics , stereochemistry , inorganic chemistry , organic chemistry

The first polyoxomolybdates with an Mo II NO instead of an Mo IV O group are compounds 2 and 3 . They were obtained by reductive nitrosylation of complex 1 with hydroxylamine in methanol. Pentamolybdate 2 is transformed into hexamolybdate 3 upon dissolution, for example in CH 2 Cl 2 . The structures of both title compounds are derived from the Lindgvist structure [Mo 6 O 19 ] 2⊖ .

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