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Multiple “Remote Functionalization” of Different Sites in Flexible Molecules by “Anchored” Bare Fe I Ions
Author(s) -
Czekay Gregor,
Eller Karsten,
Schröder Detlef,
Schwarz Helmut
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912771
Subject(s) - alkene , alkane , surface modification , fragmentation (computing) , alkyl , tandem , chemistry , ion , molecule , hydrogen , stereochemistry , hydrocarbon , organic chemistry , materials science , computer science , catalysis , composite material , operating system
Regiospecific, consecutive elimination of alkene and hydrogen —that turns out to be the pathway for what is formally an alkane elimination from the Fe ⊕ complex of the α‐branched carbonitrile 1 . Both alkyl chains of 1 participate in this fragmentation, as shown by tandem MS experiments. R(CH 2 ) 5 CD 3 , R′C 3 H 7 .