Synthesis and Structure of [(C 5 H 5 ) 2 TiS 4 AsCH 3 ]—a New Reagent for the Synthesis of Sulfur‐Rich Heterocycles | Zendy

Steudel Ralf | Zendy; Holz Birger | Zendy; Pickardt Joachim | Zendy

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Synthesis and Structure of [(C 5 H 5 ) 2 TiS 4 AsCH 3 ]—a New Reagent for the Synthesis of Sulfur‐Rich Heterocycles

Author(s) -

Steudel Ralf,

Holz Birger,

Pickardt Joachim

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198912691

Subject(s) - reagent , bimetallic strip , polysulfide , sulfur , chemistry , cleavage (geology) , stereochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , materials science , catalysis , electrode , fracture (geology) , electrolyte , composite material

The cleavage of binuclear titanocene polysulfide complexes [reaction (a)] is useful in the synthesis of the title compound 1 . Reaction probably occurs in an analogous fashion with many elemental dihalides (ECl 2 or R x EC1 2 ) and should therefore open the way to a wide variety of new titanocene complexes. Compound 1 contains a bimetallic heterocycle that functions as a transfer reagent for S 4 AsCH 3 .

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