Spontaneous Oxidation and in‐situ Polymerization of Pyrrole in Channels of the Three‐Dimensional Coordination Polymer [(Me 3 Sn) 3 Fe  III  (CN) 6 ]∞ | Zendy

Brandt Peter | Zendy; Fischer R. Dieter | Zendy; Martinez Enrique Sanchez | Zendy; Calleja Ricardo Diaz | Zendy

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Spontaneous Oxidation and in‐situ Polymerization of Pyrrole in Channels of the Three‐Dimensional Coordination Polymer [(Me 3 Sn) 3 Fe III (CN) 6 ]∞

Author(s) -

Brandt Peter,

Fischer R. Dieter,

Martinez Enrique Sanchez,

Calleja Ricardo Diaz

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198912651

Subject(s) - polypyrrole , polymerization , redox , stoichiometry , pyrrole , polymer , polymer chemistry , chemistry , coordination polymer , conductive polymer , electrode , inorganic chemistry , organic chemistry

Precursors to highly conducting polypyrrole (Ppy) are formed in the lipophilic channels of 1 subsequent to a spontaneous, strictly stoichiometric [N(Ppy)/Fe = 1/1] redox reaction. In view of the diameter of the channel (6.8 Å) the entrapped Ppy should be free of cross‐linking (thus approximating a “molecular wire”).

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