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Spontaneous Oxidation and in‐situ Polymerization of Pyrrole in Channels of the Three‐Dimensional Coordination Polymer [(Me 3 Sn) 3 Fe III (CN) 6 ]∞
Author(s) -
Brandt Peter,
Fischer R. Dieter,
Martinez Enrique Sanchez,
Calleja Ricardo Diaz
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912651
Subject(s) - polypyrrole , polymerization , redox , stoichiometry , pyrrole , polymer , polymer chemistry , chemistry , coordination polymer , conductive polymer , electrode , inorganic chemistry , organic chemistry
Precursors to highly conducting polypyrrole (Ppy) are formed in the lipophilic channels of 1 subsequent to a spontaneous, strictly stoichiometric [N(Ppy)/Fe = 1/1] redox reaction. In view of the diameter of the channel (6.8 Å) the entrapped Ppy should be free of cross‐linking (thus approximating a “molecular wire”).