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Efficient Ion Exchangers and Receptors for Organic and Organometallic Cations
Author(s) -
Eller Stefan,
Brandt Peter,
Brimah Abdul K.,
Schwarz Peter,
Fischer R. Dieter
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912631
Subject(s) - ion , organometallic chemistry , host (biology) , group 2 organometallic chemistry , chemistry , nonlinear optical , ion exchange , inorganic chemistry , metal , combinatorial chemistry , materials science , organic chemistry , catalysis , molecule , nonlinear system , physics , biology , ecology , quantum mechanics
“Free” (CH 3 ) 3 Sn ⊕ ions can be exchanged with surprising ease in polymeric metal cyanides, as demonstrated by reactions (a) and (b). Host–guest complexes, in which an inorganic solid acts as host and an organometallic or organic cation is the guest, are of considerable interest with respect to the development of materials with nonlinear optical properties.