Trinacrene – a Product of Structure‐Directed Synthesis | Zendy

Ashton Peter R. | Zendy; Isaacs Neil S. | Zendy; Kohnke Franz H. | Zendy; D'Alcontres Guglielmo Stagno | Zendy; Stoddart J. Fraser | Zendy

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Trinacrene – a Product of Structure‐Directed Synthesis

Author(s) -

Ashton Peter R.,

Isaacs Neil S.,

Kohnke Franz H.,

D'Alcontres Guglielmo Stagno,

Stoddart J. Fraser

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198912611

Subject(s) - symmetry (geometry) , product (mathematics) , cage , chemistry , combinatorial chemistry , crystallography , stereochemistry , mathematics , combinatorics , geometry

Trinacrene (1) is a promising—and very attractive‐new cage compound with a name derived from an old designation for Sicily (Trinacrien). The synthesis of 1 was accomplished in two steps involving six (2 × 3) Diels–Alder reactions and highly symmetrical precursors, the second step being a high‐pressure reaction (10 kbar). Compound 1 displays D 3 h symmetry and gives only the predicted five 1 H NMR signals.

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