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A Distillable C ‐ and N ‐Silylated Nitrile Imine
Author(s) -
Castan Florence,
Baceiredo Antoine,
Bertrand Guy
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912501
Subject(s) - imine , nitrile , carbodiimide , adduct , chemistry , medicinal chemistry , photochemistry , polymer chemistry , organic chemistry , catalysis
Compound 1 should be regarded as the synthetic equivalent of. The SiN bond is quite easily cleaved, and so is the SiC bond. Thus, 1 rearranges photochemically to carbodiimide. Reaction with dipolarophiles at room temperature leads to the expected [2 + 3] adducts.
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