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Biomimetic Synthesis of an Inverted Porphyrinoid with Peripheral N Atoms
Author(s) -
Schumacher KarlHeinz,
Franck Burchard
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912431
Subject(s) - yield (engineering) , molecule , nanotechnology , materials science , small molecule , chemistry , crystallography , organic chemistry , composite material , biochemistry
Nitrogen atoms on the periphery rather than inside the molecule characterize inverted porphyrinoids. The first such species, 1 , was synthesized in 71 % yield via a biomimetic route starting from hydroxymethylpyrrole 2 .
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