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P 14 i Pr 4 – The First Hexacyclic Organophosphane
Author(s) -
Baudler Marianne,
Jachow Harald,
Lieser Bernhard,
Tebbe KarlFriedrich,
Fehér Magda
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198912311
Subject(s) - norbornane , diastereomer , thermal decomposition , decomposition , chemistry , phase (matter) , stereochemistry , crystallography , organic chemistry
Compound 1 is made up of two norbornane like P 7 units coupled in a unique way. It results from thermolysis of a mixture of bi‐and tri‐cyclic isopropylphosphanes and represents the first tetradecaphosphane to be characterized structurally. According to 1 H{ 31 P} NMR data, the configurational isomer present in the crystalline phase equilibrates in solution with two diastereomers.