[VO(O 2 C t Bu) 3 ] and [V 6 O 6 (μ‐O) 4 (μ‐O 2 CPh) 9 ]. Structural Characterization of a Mononuclear V v  and a (2 + 4)‐Nuclear V IV V       5    V     Carboxylato Complex. Models for Vanadate‐Dependent Peroxidases | Zendy

Rehder Dieter | Zendy; Priebsch Wolfgang | Zendy; von Oeynhausen Margen | Zendy

Premium

[VO(O 2 C t Bu) 3 ] and [V 6 O 6 (μ‐O) 4 (μ‐O 2 CPh) 9 ]. Structural Characterization of a Mononuclear V v and a (2 + 4)‐Nuclear V IV V 5 V Carboxylato Complex. Models for Vanadate‐Dependent Peroxidases

Author(s) -

Rehder Dieter,

Priebsch Wolfgang,

von Oeynhausen Margen

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198912211

Subject(s) - vanadium , center (category theory) , crystallography , pentagonal bipyramidal molecular geometry , chemistry , stereochemistry , type (biology) , atom (system on chip) , inorganic chemistry , crystal structure , geology , computer science , embedded system , paleontology

The two title compounds, prepared from VOC1 3 and the silver salts of pivalic and benzoic acids , are interesting models for the structure of the vanadium center in haloperoxidases from marine brown algae. The V v center in crystalline pivalate complex 1 displays pentagonal‐bipyramidal coordination. However, IR and 51 V NMR data suggest that in solution the vanadium atom is only sixfold coordinated. The second title substance, which is hexanuclear, is an entirely new type of multinuclear oxovanadium compound with a twist‐boat V 6 structure.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research