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Di(4‐pyridinio)‐, Di(2‐benzothiazolio)‐, Di(2‐[1,3‐dithiolylio])‐ and Diformyltetraaza[14]annulenes and Tetraaza[14]annulenylene‐Homologous Tetrathiafulvalenes
Author(s) -
Adams Florian,
Gompper Rudolf
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198910631
Subject(s) - annulene , deprotonation , cationic polymerization , chemistry , tetrathiafulvalene , ring (chemistry) , stereochemistry , crystallography , medicinal chemistry , polymer chemistry , ion , molecule , organic chemistry
A possible route to new donors for the preparation of organic and metallic superconductors is provided by the title compounds. In contrast to the preceding communication, the cationic substituents in 1 (see above) are joined to the ring through a C atom. Deprotonation of 1 , X = SCHCHS, affords a homologue (shown on the right) of tetrathiafulvalene, the archetypal donor.