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A Polymeric Technetium Compound of the Composition [Tc 2 O 3 (C 5 Me 5 )] n
Author(s) -
Kanellakopulos Basil,
Nuber Bernd,
Raptis Konstantinos,
Ziegler Manfred L.
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198910551
Subject(s) - rhenium , technetium , crystallography , group 2 organometallic chemistry , chemistry , materials science , molecule , inorganic chemistry , nuclear chemistry , organic chemistry
The polymeric “polydecker compounds” 1 , not the expected [Cp * TcO 3 ], are obtained upon reaction of [Cp * Tc(CO) 3 ] with H 2 O 2 —in contrast to the analogous rhenium compound, which gives [Cp * ReO 3 ]. In the structure of 1 , three μ‐oxo ligands each bridge two Tc atoms. The distance between the Tc atoms is extremely short. The coordination of the Tc atoms is completed by the Cp * rings (Cp * = C 5 Me 5 ).