A Polymeric Technetium Compound of the Composition [Tc 2 O 3 (C 5 Me 5 )] n | Zendy

Kanellakopulos Basil | Zendy; Nuber Bernd | Zendy; Raptis Konstantinos | Zendy; Ziegler Manfred L. | Zendy

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A Polymeric Technetium Compound of the Composition [Tc 2 O 3 (C 5 Me 5 )] n

Author(s) -

Kanellakopulos Basil,

Nuber Bernd,

Raptis Konstantinos,

Ziegler Manfred L.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198910551

Subject(s) - rhenium , technetium , crystallography , group 2 organometallic chemistry , chemistry , materials science , molecule , inorganic chemistry , nuclear chemistry , organic chemistry

The polymeric “polydecker compounds” 1 , not the expected [Cp * TcO 3 ], are obtained upon reaction of [Cp * Tc(CO) 3 ] with H 2 O 2 —in contrast to the analogous rhenium compound, which gives [Cp * ReO 3 ]. In the structure of 1 , three μ‐oxo ligands each bridge two Tc atoms. The distance between the Tc atoms is extremely short. The coordination of the Tc atoms is completed by the Cp * rings (Cp * = C 5 Me 5 ).

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