A New Coordinating Chiral Lithium Amide | Zendy

Barr Donald | Zendy; Berrisford David J. | Zendy; Jones Raymond V. H. | Zendy; Slawin Alexandra M. Z. | Zendy; Snaith Ronald | Zendy; Stoddart J. Fraser | Zendy; Williams David J. | Zendy

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A New Coordinating Chiral Lithium Amide

Author(s) -

Barr Donald,

Berrisford David J.,

Jones Raymond V. H.,

Slawin Alexandra M. Z.,

Snaith Ronald,

Stoddart J. Fraser,

Williams David J.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198910441

Subject(s) - lithium amide , deprotonation , amide , lithium (medication) , dimer , amine gas treating , chemistry , solid state , polymer chemistry , medicinal chemistry , organic chemistry , catalysis , ion , enantioselective synthesis , medicine , endocrinology

The C 2 ‐symmetric ( R,R )‐di(α‐methoxymethylbenzyl)amine 1 , synthesized from ( R )‐phenylglycinol and α‐methoxyacetophenone, yields a lithium amide 2 upon lithiation with n BuLi. In the solid state and in solution, 2 is present as a dimer. 4‐ tert ‐Butylcyclohexanone could be asymmetrically deprotonated with this lithium amide.

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