One‐Dimensional Metal Chains in a Chiral Environment — The Crystal Structure of Helical Bis(dicarbonylrhodium( I ))‐3,3′‐hexafluoroglutarylbis‐(1 R )‐camphorate | Zendy

Schurig Volker | Zendy; Gaus Hans | Zendy; Scheer Peter | Zendy; Walz Leonhard | Zendy; von Schnering Hans Georg | Zendy

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One‐Dimensional Metal Chains in a Chiral Environment — The Crystal Structure of Helical Bis(dicarbonylrhodium( I ))‐3,3′‐hexafluoroglutarylbis‐(1 R )‐camphorate

Author(s) -

Schurig Volker,

Gaus Hans,

Scheer Peter,

Walz Leonhard,

von Schnering Hans Georg

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198910191

Subject(s) - rhodium , diastereomer , stacking , crystallography , chemistry , metal , stereochemistry , crystal structure , chirality (physics) , solid state , molecule , chiral symmetry , catalysis , physics , organic chemistry , nambu–jona lasinio model , quantum mechanics , quark

Interesting effects were observed in the molecular stacking of the chiral Binuclear rhodium(i) complex 1 . Both rhodium atoms are incorporated into a single one‐dimensional “rhodium chain”. The stacks consist alternately of two P and two M helices. Owing to stereoisomerism in the solid state, energetically different diastereoisomers, (1 R )‐( P )(1 R ) and (1 R )‐( M )‐(1 R ), are present.

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