Premium
One‐Dimensional Metal Chains in a Chiral Environment — The Crystal Structure of Helical Bis(dicarbonylrhodium( I ))‐3,3′‐hexafluoroglutarylbis‐(1 R )‐camphorate
Author(s) -
Schurig Volker,
Gaus Hans,
Scheer Peter,
Walz Leonhard,
von Schnering Hans Georg
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198910191
Subject(s) - rhodium , diastereomer , stacking , crystallography , chemistry , metal , stereochemistry , crystal structure , chirality (physics) , solid state , molecule , chiral symmetry , catalysis , physics , organic chemistry , nambu–jona lasinio model , quantum mechanics , quark
Interesting effects were observed in the molecular stacking of the chiral Binuclear rhodium(i) complex 1 . Both rhodium atoms are incorporated into a single one‐dimensional “rhodium chain”. The stacks consist alternately of two P and two M helices. Owing to stereoisomerism in the solid state, energetically different diastereoisomers, (1 R )‐( P )(1 R ) and (1 R )‐( M )‐(1 R ), are present.