[Mes 2 SbCu(PMe 3 ) 2 ] 2 : The First Cu I  Antimonide | Zendy

Cowley Alan H. | Zendy; Jones Richard A. | Zendy; Nunn Christine M. | Zendy; Westmoreland Donald L. | Zendy

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[Mes 2 SbCu(PMe 3 ) 2 ] 2 : The First Cu I Antimonide

Author(s) -

Cowley Alan H.,

Jones Richard A.,

Nunn Christine M.,

Westmoreland Donald L.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198910181

Subject(s) - antimonide , protonation , lithium (medication) , reduction (mathematics) , planar , chemistry , crystallography , medicinal chemistry , photochemistry , mathematics , geometry , organic chemistry , computer science , ion , computer graphics (images) , medicine , endocrinology

A planar Cu 2 Sb 2 framework characterizes the structure of the title complex 1 , which is moderately stable in the crystalline form in the absence of light and air, but rapidly decomposes in solution. The Cu 1 antimonide was prepared by lithiation of Mes 2 SbH with nBuLi followed by reaction with CuCI and Me 3 P in THF. Mes 2 SbH, the structure of which was also determined, is obtained from Mes 3 Sb by reduction with lithium powder and protonation with Me 3 NHCl.

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