Amide Bond Scission via Bifunctional Activation with Bimetallic Porphyrin Systems with Two Different Metal Centers | Zendy

Aoyama Yasuhiro | Zendy; Motomura Tadahiro | Zendy; Ogoshi Hisanobu | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Amide Bond Scission via Bifunctional Activation with Bimetallic Porphyrin Systems with Two Different Metal Centers

Author(s) -

Aoyama Yasuhiro,

Motomura Tadahiro,

Ogoshi Hisanobu

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198909211

Subject(s) - bimetallic strip , bifunctional , catalysis , adduct , porphyrin , bond cleavage , chemistry , methanol , amide , metal , polymer chemistry , transesterification , organic chemistry

Multicenter interactions play an important role in biomimetic catalysts and receptors. It has now been possible to develop a Rh III Ag I system which accelerates the methanolysis of p ‐nitroacetanilide (stoichiometrically) and the transesterification of ethyl acetate with methanol (catalytically). 1 shows the double activation in the intermediary adduct.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research