The Novel Complex [LRu IV (μ‐O) 3 Ru IV L][PF 6 ] 2 ·H 2 O–a Molecular Section of the Structures of BaRu IV O 3  (High‐Pressure Phase) and Ba 5/6 Sr 1/6 Ru IV O 3 | Zendy

Neubold Peter | Zendy; Della Vedova Beatriz S. P. C. | Zendy; Wieghardt Karl | Zendy; Nuber Bernd | Zendy; Weiss Johannes | Zendy

Premium

The Novel Complex [LRu IV (μ‐O) 3 Ru IV L][PF 6 ] 2 ·H 2 O–a Molecular Section of the Structures of BaRu IV O 3 (High‐Pressure Phase) and Ba 5/6 Sr 1/6 Ru IV O 3

Author(s) -

Neubold Peter,

Della Vedova Beatriz S. P. C.,

Wieghardt Karl,

Nuber Bernd,

Weiss Johannes

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198907631

Subject(s) - ternary operation , valence (chemistry) , metal , crystallography , ruthenium , chemistry , unpaired electron , group 2 organometallic chemistry , formula unit , electron , inorganic chemistry , molecule , materials science , crystal structure , physics , catalysis , nuclear physics , organic chemistry , computer science , programming language

A better understanding of the magnetic properties of ternary oxides such as BaRuO 3 and of metal–metal interactions might be offered by complex 3 and the two other new compounds 1 and 2 . These compounds were synthesized as PF 6 salts. Blue 1 can be oxidized to green 3 via 2 (yellow). Compounds 1 and 3 contain short Ru‐Ru bonds. Compound 3 can be converted electrochemically into the mixed valence Ru IV Ru v and Ru III Ru IV complexes. In 3 , two unpaired electrons are present per formula unit (L = N , N ′, N ″‐trimethyl‐1,4,7‐triazacyclononane).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research