PbMo 5 O 8  and Tl 0.8 Sn 0.6 Mo 7 O 11 , Novel Clusters of Molybdenum and Thallium | Zendy

Dronskowski R. | Zendy; Simon A. | Zendy

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PbMo 5 O 8 and Tl 0.8 Sn 0.6 Mo 7 O 11 , Novel Clusters of Molybdenum and Thallium

Author(s) -

Dronskowski R.,

Simon A.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198907581

Subject(s) - octahedron , crystallography , cluster (spacecraft) , molybdenum , materials science , chemistry , crystal structure , inorganic chemistry , computer science , programming language

Clusters with three edge‐sharing Mo 6 octahedra and pairwise linked TI atoms characterize the structure of 1 , which fills a gap in the series of compounds containing fragments of the infinite Mo 4 O 6 chain. Compounds are now known that have isolated octahedra or up to five edge‐sharing octahedra. The electron count for 1 and for the Pb compound 2 (two condensed octahedra) indicates the existence of inter‐cluster bonds and an oxidation state of 2 for TI and Sn or Pb. TI 0.8 Sn 0.6 Mn 7 O 11 1 PbMo 5 O 8 2

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