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Triple‐Decker Complexes as Intermediates in Ring‐Ligand Transfers
Author(s) -
Herberich Gerhard E.,
Dunne Barry J.,
Heßner Bernd
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198907371
Subject(s) - ring (chemistry) , ligand (biochemistry) , chemistry , stereochemistry , receptor , organic chemistry , biochemistry
The first borole complexes and, at the same time, the first triple‐decker complexes of rhenium and iridium were obtained by ring‐ligand transfers of 1 or 2 via triple‐decker intermediates such as 3 to give complexes such as 4 . Thus, in addition to the earlier postulated monofacial bridging, bifacial bridging is possible in such transfers.