catena ‐Poly[bis‐μ‐( o ‐oxyphenyleneoxy)silicon]: Crystal Structure of the Orthosilicate of Catechol | Zendy

Hönle Wolfgang | Zendy; DettlaffWeglikowska Urszula | Zendy; Walz Leonard | Zendy; von Schnering Hans Georg | Zendy

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catena ‐Poly[bis‐μ‐( o ‐oxyphenyleneoxy)silicon]: Crystal Structure of the Orthosilicate of Catechol

Author(s) -

Hönle Wolfgang,

DettlaffWeglikowska Urszula,

Walz Leonard,

von Schnering Hans Georg

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198906231

Subject(s) - catechol , orthosilicate , crystallography , silicon , crystal structure , polymer , planar , chemistry , materials science , tetraethyl orthosilicate , stereochemistry , nanotechnology , organic chemistry , computer science , computer graphics (images)

The title compound 1, which is of special interest because of the postulated square planar SiO 4 coordination , forms one‐dimensional infinite polymers with tetrahedrally bound silicon. Both ligands act as bridging functions in the catena structure. The polymer contains ten‐membered C 4 O 4 Si 2 rings.

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