Synthesis and Analysis of Polymetallaphosphazenes | Zendy

Roesky Herbert W. | Zendy; Lücke Michaela | Zendy

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Synthesis and Analysis of Polymetallaphosphazenes

Author(s) -

Roesky Herbert W.,

Lücke Michaela

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198904931

Subject(s) - polystyrene , polymer , calibration , xylene , materials science , viscosity , analytical chemistry (journal) , polymer chemistry , chemistry , chromatography , organic chemistry , composite material , physics , toluene , quantum mechanics

Polymers containing metal atoms in the main chain are formed when 1 is heated in xylene. The average molecular weights of the polymers were found to be 24 000 (MMo) and 37 000 (MW) by viscosity measurements. Two major components ( M r = 11800 and 34 500) for M Mo and three ( M r = 11800, 34 500, 68 000) for M W were found by HPLC analysis using polystyrene calibration standards.

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