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Radical Anion Salts of Naphthalenetetracarboxylic Acid Derivatives—a Novel Class of Electrically Conducting Compounds
Author(s) -
Heywang Gerhard,
Born Liborius,
Fitzky HansGeorg,
Hassel Tillmann,
Hocker Jürgen,
Müller HansKlaus,
Pittel Bernd,
Roth Sigmar
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198904831
Subject(s) - stacking , electrical conductor , ion , conductivity , polymer chemistry , diimide , class (philosophy) , crystal structure , electrical resistivity and conductivity , materials science , chemistry , organic chemistry , molecule , composite material , computer science , physics , perylene , quantum mechanics , artificial intelligence
The search for new organic conductors has led to a broadly variable class consisting of the radical anion salts of naphthalenetetracarboxylic dianhydride and diimide. The X‐ray structure analysis of the complex 1 (single crystal conductivity σ 20°C = 10 S cm −1 ) revealed a stacking of anionic units characteristic of one‐dimensional conductors.