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17‐ to 19‐Electron Pentamethylcyclopentadienyl Iron Dithiocarbamate Complexes. Formation of a Cp * Fe IV Complex
Author(s) -
Desbois MarieHélène,
Astruc Didier
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198904601
Subject(s) - dithiocarbamate , chemistry , electron , medicinal chemistry , crystallography , physics , organic chemistry , nuclear physics
The “electron‐reservoir” properties of ⊖ SC(S)NMe 2 are demonstrated by the facile interconversion of the 17‐electron complexes 1 ⊕ and the 18‐electron complexes 1 (L = CO, MeCN, Me 2 CO, CH 2 Cl 2 ) as well as by the reaction of complex 1 ⊕ , L = CO, with NaSC(S)NMe 2 ·2H 2 O to give the symmetrical complex 1 , L = SC(S)NMe 2 , with reduction of water.