Premium
2‐Pentyltricyclo[1.1.1.0 1,3 ]pentane and Its Homopolymer, a Soluble Poly([1.1.1]propellane)
Author(s) -
Opitz Klaus,
Schlüter ArnulfDieter
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198904561
Subject(s) - propellane , pentane , chemistry , polymerization , polymer , polymer chemistry , bicyclic molecule , stereochemistry , organic chemistry
The pentyl‐substituted poly([1.1.1]propellane) 2 is a soluble polymer with a stiff main chain. It was obtained from the propellane 1 , which is accessible on a 5‐g scale in a three‐step synthesis. Compound 2 is formed by anionically initiated, ring‐opening polymerization of 1 .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom