Selenium‐Catalyzed Synthesis of  S ‐Alkyl Thiocarbamates from Amines, Carbon Monoxide, Sulfur, and Alkyl Halides | Zendy

Sonoda Noboru | Zendy; Mizuno Takumi | Zendy; Murakami Sinkichi | Zendy; Kondo Kiyoshi | Zendy; Ogawa Akiya | Zendy; Ryu Ilhyong | Zendy; Kambe Nobuaki | Zendy

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Selenium‐Catalyzed Synthesis of S ‐Alkyl Thiocarbamates from Amines, Carbon Monoxide, Sulfur, and Alkyl Halides

Author(s) -

Sonoda Noboru,

Mizuno Takumi,

Murakami Sinkichi,

Kondo Kiyoshi,

Ogawa Akiya,

Ryu Ilhyong,

Kambe Nobuaki

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198904521

Subject(s) - thiocarbamates , alkyl , chemistry , halide , selenium , sulfur , yield (engineering) , carbon monoxide , catalysis , medicinal chemistry , sulfide , organic chemistry , selenide , materials science , metallurgy

1 atm CO, 30°C, and 10 mol% selenium —these are the conditions under which the S ‐alkyl thiocarbamates 1 were obtained in 41–100% yield according to Equation (a). The presumed intermediates are selenocarbamates, carbonyl selenide, and carbonyl sulfide. R 1 ,R 2 = Et, n Pr, n Pr, n Bu, Ph, H; R 3 = Me, Et, PhCH 2 , 4‐ClC 6 H 4 CH 2 .

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